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spandex
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{{Distinguish|Spanx}}
missing image!
- Cynthia Barboza.jpg -
American volleyball player Cynthia Barboza wearing spandex shorts
Spandex, Lycra or elastane is a synthetic fiber known for its exceptional elasticity. It is a polyether-polyurea copolymer that was invented in 1958 by chemist Joseph Shivers at DuPont's Benger Laboratory in Waynesboro, Virginia.{{US Patent |3023192}}, "Segmented copolyetherester elastomers" filed May 29, 1958, issued Feb 27, 1962Flynn, Elizabeth and Patel, Sarah (2016) The Really Useful Primary Design and Technology Book: Subject Knowledge and Lesson Ideas New York: Routledge. p.86. {{ISBN|9781317402565}}Teegarden, David M. (2004) Polymer Chemistry: Introduction to an Indispensable Science NSTA Press. p.149. {{ISBN|9780873552219}}Editors of Time-Life (2016) TIME-LIFE American Inventions: Big Ideas That Changed Modern Life Time-Life Books. {{ISBN|9781683306313}}Moskowitz, Sanford L. (2016) Advanced Materials Innovation: Managing Global Technology in the 21st Century Wiley. {{ISBN|9780470508923}} The name "spandex" is an anagram of the word "expands".Kadolph, Sara J. (2010) Textiles. Pearson. {{ISBN|9780135007594}} It is the preferred name in North America; in continental Europe it is referred to by variants of "elastane", i.e. (France), (Germany, Sweden), (Spain), (Italy) and (Netherlands), and is known in the UK, Ireland, Portugal, Spain, Brazil, Argentina, Australia, New Zealand and Israel primarily as Lycra. Brand names for spandex include Lycra (made by Koch subsidiary Invista, previously part of DuPont), Elaspan (also Invista), Acepora (Taekwang), Creora (Hyosung), INVIYA (Indorama Corporation), ROICA and Dorlastan (Asahi Kasei), Linel (Fillattice), and ESPA (Toyobo).

Invention

Dupont textiles scientist Joseph C. Shivers was determined to find a fiber to replace rubber in garments. He made a breakthrough in the early 1950s when he used an intermediate substance to modify Dacron polyester.WEB,weblink" title="web.archive.org/web/20131203014041weblink">weblink Wayback Machine, 2013-12-03, 2018-11-26, This modification produced a stretchy fiber that could withstand high temperatures. After nearly a decade of research the fiber was perfected in 1959. Originally called Fiber K, DuPont chose the trade name Lycra to distinguish its brand of spandex fiber.WEB,weblink WHAT'S THAT STUFF? - SPANDEX, pubs.acs.org, 2018-12-06,

Production

{{multiple image| align = left| direction = horizontal| image1 = Polyurethane Fibers (micro photo).jpg| width1 = 267
Optical microscope>an optical microscope (cross-polarized light illumination, magnification 100x)| image2 = Spandex fiber.jpg| width2 = 134| caption2 = Spandex fiber }}Spandex fibers are produced in four ways: melt extrusion, reaction spinning, solution dry spinning, and solution wet spinning. All of these methods include the initial step of reacting monomers to produce a prepolymer. Once the prepolymer is formed, it is reacted further in various ways and drawn out to make the fibers.The solution dry spinning method is used to produce over 94.5% of the world's spandex fibers,"How spandex is made" from How Products Are Made and the process has five steps:
  • 1. The first step is to produce the prepolymer. This is done by mixing a macroglycol with a diisocyanate monomer. The two compounds are mixed in a reaction vessel to produce a prepolymer. A typical ratio of glycol to diisocyanate is 1:2.
  • 2. The prepolymer is further reacted with an equal amount of diamine. This reaction is known as chain extension reaction. The resulting solution is diluted with a solvent (DMAc) to produce the spinning solution. The solvent helps make the solution thinner and more easily handled, and then it can be pumped into the fiber production cell.
  • 3. The spinning solution is pumped into a cylindrical spinning cell where it is cured and converted into fibers. In this cell, the polymer solution is forced through a metal plate called a spinneret. This causes the solution to be aligned in strands of liquid polymer. As the strands pass through the cell, they are heated in the presence of a nitrogen and solvent gas. This process causes the liquid polymer to react chemically and form solid strands.
  • 4. As the fibers exit the cell, an amount of solid strands are bundled together to produce the desired thickness. Each fiber of spandex is made up of many smaller individual fibers that adhere to one another because of the natural stickiness of their surface.
  • 5. The resulting fibers are then treated with a finishing agent which can be magnesium stearate or a polymer. This treatment prevents the fibers' sticking together and aids in textile manufacture. The fibers are then transferred through a series of rollers onto a spool.
File:Spandex biker by Ed Yourdon.jpg|thumb|right|187px|Cyclist wearing a pair of spandex shorts and a cycling jerseycycling jersey(File:World Junior Ski Championship 2010 Hinterzarten Mattel Lemare Clair Espiau 133.JPG|alt=|thumb|187x187px|French Ski team (2010) wearing Spandex.)

Role in fashion

In the post World War II era, DuPont Textiles Fibers Department, which was formed in 1952, became its most popular division, dominating the synthetic fiber market worldwide.{{Citation|last=O'Connor|first=Kaori|publisher=University of Pennsylvania Press|isbn=9780812206050|doi=10.9783/9780812206050.207|title=Producing Fashion|year=2008|chapter=CHAPTER ELEVEN. The Body and the Brand: How Lycra Shaped America}} At this time, women began to emerge as a significant group of consumers because of their need for underwear and hosiery. DuPont conducted market research to find out what women wanted from textiles, then began developing fibers to meet their needs. The "need" was a better fiber solution for women's girdles, which were commonly made of rubber at the time. DuPont became interested in developing a synthetic elastic fiber in the 1930s, which was perfected by chemist Joseph Shivers in 1959. Spandex's transformative nature allowed it to be incorporated into other garments besides girdles and undergarments. DuPont launched an extensive publicity campaign for its Lycra brand, taking advertisements and full-page ads in top women's magazines such as Vogue, Glamour, Harper Bazaar, Mademoiselle, McCalls, Ladies Home Journal, and Good Housekeeping. Fashion's original style icon, Audrey Hepburn helped catapult the brand on and off-screen in the late 50's; models and actress like Joan Collins and Anne-Margret followed Hepburns aesthetic by posing in Lycra clothing for photo shoots and magazine covers.WEB,weblink What Came First: The Yoga Pant Or The Skinny Jean?, Clark, Meaghan, www.refinery29.com, en, 2018-12-11, By the mid-1970s, girdle sales began to drop with the emergence of the Women's Liberation Movement. Girdles came to be associated with anti-independence and emblematic of an era that was quickly passing away. DuPont was not ready to abandon a market that they were significantly reliant on. In response, DuPont reimagined Lycra as the aerobic fitness movement emerged in the 1970s. This expansion furthered at the 1968 Winter Olympic Games when the French ski team wore Lycra garments to compete.{{Citation|last=The Sydney Morning Herald|title=Lycra: a brief history|url=https://www.youtube.com/watch?v=vvwIlHUIqAU|access-date=2018-12-11}} This popularized the brand as essential athletic wear because of its flexible and lightweight material. The fiber proved to be especially popular in mid-thigh-length shorts worn by cyclists. By the 1980s, the fitness trend had reached its height in popularity and fashionistas began wearing shorts on the street.WEB,weblink Spandex - Fashion, Costume, and Culture: Clothing, Headwear, Body Decorations, and Footwear through the Ages, www.fashionencyclopedia.com, 2018-12-11, Spandex proved such a popular fiber in the garment industry that by 1987 DuPont had trouble meeting worldwide demand. In the 1990s a variety of other items made with Spandex proved popular, including a successful line of body-shaping foundation garments sold under the trade name Bodyslimmers. As the decade progressed, shirts, pants, dresses, and even shoes were being made with spandex blends, and mass-market retailers like Banana Republic were using it for menswear.

Major spandex fiber uses

The elasticity and strength (stretching up to five times its length), of spandex has been incorporated into a wide range of garments, especially in skin-tight garments. A benefit of spandex is its significant strength and elasticity and its ability to return to the original shape after stretching and faster drying than ordinary fabrics. For clothing, spandex is usually mixed with cotton or polyester, and accounts for a small percentage of the final fabric, which therefore retains most of the look and feel of the other fibers. In North America it is rare in men's clothing, but prevalent in women's. An estimated 80% of clothing sold in the United States contained spandex in 2010.NEWS,weblink Spandex Stretches To Meet U.S. Waistlines, Marisa Penaloza, 2011-12-11, 2012-01-17, NPR, File:Otago Dancers human pyramid 2.jpg|thumb|187px|A human pyramid of dancers wearing spandex zentaizentaiThe types of garments which incorporate spandex include:

Harmful environmental impact

Today most clothes containing spandex end up as non-recyclable waste once the've been worn out, as fabric blends containing spandex are difficult to recycle. JOURNAL, Removal of spandex from nylon/spandex blended fabrics by selective polymer degradation, Textile Research Journal, 84, 16–27, Yunjie Yin, Donggang Yao, Chaoxia Wang, Youjiang Wang, Textile Research Journal, Volume 84, Issue 1, January 2014, 10.1177/0040517513487790, 2014, This contributes to the pollution of the environment.

See also

References

{{Reflist}}

External links

{{Commons category|Spandex}} {{Fibers}}{{Fabric}}{{Clothing materials and parts}}


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