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ammonium phosphate

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ammonium phosphate
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{{Chembox| Verifiedfields = changed| Watchedfields = changed| verifiedrevid = 428203184| ImageFile = Ammonium phosphate.png| ImageFile1 = Triammonium-phosphate-3D-balls.png| ImageSize1 = 240px| ImageName1 = Ball-and-stick model of three ammonium cations and one phosphate anion| Reference = BOOK, Lide, David R., 1998, Handbook of Chemistry and Physics
volume =, Boca Raton, Florida, CRC Press pages = 4–42, 5–19, | IUPACName = ammonium phosphate| OtherNames = triammonium phosphate|Section1={{Chembox Identifierscorrect|chemspider}}| ChemSpiderID = 140090| InChI = 1/3H3N.H3O4P/c;;;1-5(2,3)4/h3*1H3;(H3,1,2,3,4)| InChIKey = ZRIUUUJAJJNDSS-UHFFFAOYAAcorrect|chemspider}}| StdInChI = 1S/3H3N.H3O4P/c;;;1-5(2,3)4/h3*1H3;(H3,1,2,3,4)correct|chemspider}}| StdInChIKey = ZRIUUUJAJJNDSS-UHFFFAOYSA-Ncorrect|CAS}}| CASNo = 10361-65-6| EC_number = 269-789-9changed|FDA}}| UNII = 2ZJF06M0I9| PubChem = 159282| SMILES = [O-]P([O-])([O-])=O.[NH4+].[NH4+].[NH4+]}}|Section2={{Chembox Properties| Formula = (NH4)3PO4| Appearance = White, tetrahedral crystals| Density =| MeltingPt =| BoilingPt =| Solubility = 58.0 g/100 mL (25 Â°C)acetoneJOHN RUMBLE DATE=JUNE 18, 2018 ISBN=978-1138561632 EDITION=99TH, English, | MolarMass=149.09 g/mol}}|Section3={{Chembox Hazards| GHSPictograms = {{GHS07}}| GHSSignalWord = Warning302|319}}264280305+351+338337+313|501}}| NFPA-H = 2| NFPA-F = 0| NFPA-R = 0| MainHazards =| FlashPt =| AutoignitionPt = }}|Section4={{Chembox Thermochemistry| DeltaHf = −1671.9 kJ/mol| DeltaHc =| Entropy =| HeatCapacity = }}|Section8={hide}Chembox Related| OtherCations = Trisodium phosphateTripotassium phosphate| OtherCompounds = Diammonium phosphateMonoammonium phosphate
{edih}
}}Ammonium phosphate is the inorganic compound with the formula (NH4)3PO4. It is the ammonium salt of orthophosphoric acid. A related "double salt", (NH4)3PO4.(NH4)2HPO4 is also recognized but is impractical to use. Both triammonium salts evolve ammonia. In contrast to the unstable nature of the triammonium salts, the diammonium phosphate (NH4)2HPO4 and monoammonium salt (NH4)H2PO4 are stable materials that are commonly used as fertilizers to provide plants with fixed nitrogen and phosphorus.{{Ullmann|first1=Klaus|last1=Schrödter|first2=Gerhard|last2=Bettermann|first3=Thomas |last3=Staffel|first4=Friedrich|last4=Wahl|first5=Thomas|last5=Klein||first6=Thomas|last6=Hofmann|title=Phosphoric Acid and Phosphates|year=2008|doi=10.1002/14356007.a19_465.pub3}}

Preparation of triammonium phosphate

Triammonium phosphate can be prepared in the laboratory by treating 85% phosphoric acid with 30% ammonia solution:{{cn|date=April 2019}}
H3PO4 + 3 NH3 → (NH4)3PO4
(NH4)3PO4 is a colorless, crystalline solid. The solid, which has the odor of ammonia, is readily soluble in water. The salt converts to diammonium hydrogen phosphate (NH4)2HPO4.

See also

References

{{Reflist}}{{Ammonium salts}}{{Phosphates}}{{inorganic-compound-stub}}


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