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quantum electrodynamics

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**quantum electrodynamics**(

**QED**) is the relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and special relativity is achieved. QED mathematically describes all phenomena involving electrically charged particles interacting by means of exchange of photons and represents the quantum counterpart of classical electromagnetism giving a complete account of matter and light interaction.In technical terms, QED can be described as a perturbation theory of the electromagnetic quantum vacuum. Richard Feynman called it "the jewel of physics" for its extremely accurate predictions of quantities like the anomalous magnetic moment of the electron and the Lamb shift of the energy levels of hydrogen.BOOK, Feynman, Richard, Richard Feynman, 1985, 978-0-691-12575-6, QED: The Strange Theory of Light and Matter, Princeton University Press, {{rp|Ch1}}

## History

File:Dirac 3.jpg|upright|thumb|right|Paul DiracPaul DiracThe first formulation of a quantum theory describing radiation and matter interaction is attributed to British scientist Paul Dirac, who (during the 1920s) was able to compute the coefficient of spontaneous emission of an atom.JOURNAL, P.A.M. Dirac

, Paul Adrien Maurice Dirac

, 1927

, The Quantum Theory of the Emission and Absorption of Radiation

, Proceedings of the Royal Society of London A

, 114, 243â€“65

, 10.1098/rspa.1927.0039, 1927RSPSA.114..243D

, 767,

Dirac described the quantization of the electromagnetic field as an ensemble of harmonic oscillators with the introduction of the concept of creation and annihilation operators of particles. In the following years, with contributions from Wolfgang Pauli, Eugene Wigner, Pascual Jordan, Werner Heisenberg and an elegant formulation of quantum electrodynamics due to Enrico Fermi,JOURNAL
, Paul Adrien Maurice Dirac

, 1927

, The Quantum Theory of the Emission and Absorption of Radiation

, Proceedings of the Royal Society of London A

, 114, 243â€“65

, 10.1098/rspa.1927.0039, 1927RSPSA.114..243D

, 767,

, E. Fermi

, Enrico Fermi

, 1932

, Quantum Theory of Radiation

, Reviews of Modern Physics

, 4, 1

, 87â€“132

, 10.1103/RevModPhys.4.87, 1932RvMP....4...87F, physicists came to believe that, in principle, it would be possible to perform any computation for any physical process involving photons and charged particles. However, further studies by Felix Bloch with Arnold Nordsieck,JOURNAL

, Felix Bloch

, Arnold Nordsieck

, 1937

, Note on the Radiation Field of the Electron

, Physical Review

, 52, 54â€“59

, 10.1103/PhysRev.52.54, 1937PhRv...52...54B

, 2

, Bloch

, F.

, Nordsieck

, A.

, and Victor Weisskopf,JOURNAL
, Enrico Fermi

, 1932

, Quantum Theory of Radiation

, Reviews of Modern Physics

, 4, 1

, 87â€“132

, 10.1103/RevModPhys.4.87, 1932RvMP....4...87F, physicists came to believe that, in principle, it would be possible to perform any computation for any physical process involving photons and charged particles. However, further studies by Felix Bloch with Arnold Nordsieck,JOURNAL

, Felix Bloch

, Arnold Nordsieck

, 1937

, Note on the Radiation Field of the Electron

, Physical Review

, 52, 54â€“59

, 10.1103/PhysRev.52.54, 1937PhRv...52...54B

, 2

, Bloch

, F.

, Nordsieck

, A.

, V. F. Weisskopf

, Victor Weisskopf

, 1939

, On the Self-Energy and the Electromagnetic Field of the Electron

, Physical Review

, 56, 1

, 72â€“85

, 10.1103/PhysRev.56.72

, Victor Weisskopf

, 1939

, On the Self-Energy and the Electromagnetic Field of the Electron

, Physical Review

, 56, 1

, 72â€“85

, 10.1103/PhysRev.56.72

Perturbation theory (quantum mechanics)>perturbation theory, a problem already pointed out by Robert Oppenheimer.JOURNAL
, R. Oppenheimer
File:Hans Bethe.jpg|upright|thumb|left|Hans BetheHans BetheDifficulties with the theory increased through the end of the 1940s. Improvements in microwave technology made it possible to take more precise measurements of the shift of the levels of a hydrogen atom,JOURNAL
, Robert Oppenheimer , 1930 , Note on the Theory of the Interaction of Field and Matter , Physical Review , 35, 461â€“77 , 10.1103/PhysRev.35.461, 1930PhRv...35..461O , 5, At higher orders in the series infinities emerged, making such computations meaningless and casting serious doubts on the internal consistency of the theory itself. With no solution for this problem known at the time, it appeared that a fundamental incompatibility existed between special relativity and quantum mechanics. , Willis Lamb
JOURNAL
, Robert Retherford , 1947 , Fine Structure of the Hydrogen Atom by a Microwave Method , Physical Review , 72, 241â€“43 , 10.1103/PhysRev.72.241, 1947PhRv...72..241L , 3 , Lamb , Willis , Retherford , Robert , now known as the Lamb shift and magnetic moment of the electron. , Polykarp Kusch
A first indication of a possible way out was given by Hans Bethe in 1947, after attending the Shelter Island Conference.BOOK
, Henry M. Foley , 1948 , On the Intrinsic Moment of the Electron , Physical Review , 73, 412 , 10.1103/PhysRev.73.412 , 1948PhRv...73..412F , 3 , Foley , H.M. , Kusch , P., These experiments exposed discrepancies which the theory was unable to explain. , Schweber
JOURNAL
, Silvan , Silvan Schweber , 1994 , 978-0-691-03327-3 , QED and the Men Who Did it: Dyson, Feynman, Schwinger, and Tomonaga , Chapter 5 , 230 , Princeton University Press, While he was traveling by train from the conference to Schenectady he made the first non-relativistic computation of the shift of the lines of the hydrogen atom as measured by Lamb and Retherford. , H. Bethe
File:Feynman and Oppenheimer at Los Alamos.jpg|thumb|right|Feynman (center) and Oppenheimer (right) at Los Alamos.]]Based on Bethe's intuition and fundamental papers on the subject by Shin'ichirÅ Tomonaga,JOURNAL
, Hans Bethe , 1947 , The Electromagnetic Shift of Energy Levels , Physical Review , 72, 339â€“41 , 10.1103/PhysRev.72.339, 1947PhRv...72..339B , 4, Despite the limitations of the computation, agreement was excellent. The idea was simply to attach infinities to corrections of mass and charge that were actually fixed to a finite value by experiments. In this way, the infinities get absorbed in those constants and yield a finite result in good agreement with experiments. This procedure was named renormalization. , S. Tomonaga
JOURNAL
, Sin-Itiro Tomonaga , 1946 , On a Relativistically Invariant Formulation of the Quantum Theory of Wave Fields , Progress of Theoretical Physics , 1, 27â€“42 , 10.1143/PTP.1.27 , 2, 1946PThPh...1...27T , Julian Schwinger, , J. Schwinger
JOURNAL
, Julian Schwinger , 1948 , On Quantum-Electrodynamics and the Magnetic Moment of the Electron , Physical Review , 73, 416â€“17 , 10.1103/PhysRev.73.416, 1948PhRv...73..416S , 4, , J. Schwinger
JOURNAL
, Julian Schwinger , 1948 , Quantum Electrodynamics. I. A Covariant Formulation , Physical Review , 74, 1439â€“61 , 10.1103/PhysRev.74.1439, 1948PhRv...74.1439S , 10, Richard Feynman , R. P. Feynman
JOURNAL
, Richard Feynman , 1949 , Spaceâ€“Time Approach to Quantum Electrodynamics , Physical Review , 76, 769â€“89 , 10.1103/PhysRev.76.769, 1949PhRv...76..769F , 6, , R. P. Feynman
JOURNAL
, Richard Feynman , 1949 , The Theory of Positrons , Physical Review , 76, 749â€“59 , 10.1103/PhysRev.76.749, 1949PhRv...76..749F , 6, , R. P. Feynman
JOURNAL
, Richard Feynman , 1950 , Mathematical Formulation of the Quantum Theory of Electromagnetic Interaction , Physical Review , 80, 440â€“57 , 10.1103/PhysRev.80.440, 1950PhRv...80..440F , 3,weblink , and Freeman Dyson, , F. Dyson
JOURNAL
, Freeman Dyson , 1949 , The Radiation Theories of Tomonaga, Schwinger, and Feynman , Physical Review , 75, 486â€“502 , 10.1103/PhysRev.75.486, 1949PhRv...75..486D , 3, , F. Dyson
QED has served as the model and template for all subsequent quantum field theories. One such subsequent theory is quantum chromodynamics, which began in the early 1960s and attained its present form in the 1970s work by H. David Politzer, Sidney Coleman, David Gross and Frank Wilczek. Building on the pioneering work of Schwinger, Gerald Guralnik, Dick Hagen, and Tom Kibble,JOURNAL
, Freeman Dyson , 1949 , The S Matrix in Quantum Electrodynamics , Physical Review , 75, 1736â€“55 , 10.1103/PhysRev.75.1736, 1949PhRv...75.1736D , 11, it was finally possible to get fully covariant formulations that were finite at any order in a perturbation series of quantum electrodynamics. Shin'ichirÅ Tomonaga, Julian Schwinger and Richard Feynman were jointly awarded with a Nobel prize in physics in 1965 for their work in this area.WEB, The Nobel Prize in Physics 1965, Nobel Foundation,weblink 2008-10-09, Their contributions, and those of Freeman Dyson, were about covariant and gauge invariant formulations of quantum electrodynamics that allow computations of observables at any order of perturbation theory. Feynman's mathematical technique, based on his diagrams, initially seemed very different from the field-theoretic, operator-based approach of Schwinger and Tomonaga, but Freeman Dyson later showed that the two approaches were equivalent. Renormalization, the need to attach a physical meaning at certain divergences appearing in the theory through integrals, has subsequently become one of the fundamental aspects of quantum field theory and has come to be seen as a criterion for a theory's general acceptability. Even though renormalization works very well in practice, Feynman was never entirely comfortable with its mathematical validity, even referring to renormalization as a "shell game" and "hocus pocus".{{rp|128}} , Guralnik, G. S.
JOURNAL
, Hagen, C. R. , Kibble, T. W. B. , 1964 , Global Conservation Laws and Massless Particles , Physical Review Letters , 13, 585â€“87 , 10.1103/PhysRevLett.13.585 , 1964PhRvL..13..585G , 20, , Guralnik
, G. S. , 2009 , The History of the Guralnik, Hagen and Kibble development of the Theory of Spontaneous Symmetry Breaking and Gauge Particles , International Journal of Modern Physics A , 24, 2601â€“27 , 10.1142/S0217751X09045431 , 0907.3466, 2009IJMPA..24.2601G , 14, Peter Higgs, Jeffrey Goldstone, and others, Sheldon Lee Glashow, Steven Weinberg and Abdus Salam independently showed how the weak nuclear force and quantum electrodynamics could be merged into a single electroweak force. ## Feynman's view of quantum electrodynamics## IntroductionNear the end of his life, Richard P. Feynman gave a series of lectures on QED intended for the lay public. These lectures were transcribed and published as Feynman (1985), (QED (book)|QED: The strange theory of light and matter), a classic non-mathematical exposition of QED from the point of view articulated below.The key components of Feynman's presentation of QED are three basic actions.{{rp|85}}
A photon goes from one place and time to another place and time.
An electron goes from one place and time to another place and time.
An electron emits or absorbs a photon at a certain place and time.
File:Feynman Diagram Components.svg|thumb|right|300px|Feynman diagram elements]]These actions are represented in the form of visual shorthand by the three basic elements of Feynman diagrams: a wavy line for the photon, a straight line for the electron and a junction of two straight lines and a wavy one for a vertex representing emission or absorption of a photon by an electron. These can all be seen in the adjacent diagram.As well as the visual shorthand for the actions Feynman introduces another kind of shorthand for the numerical quantities called probability amplitudes. The probability is the square of the absolute value of total probability amplitude, text{probability} = | f(text{amplitude}) |^2. If a photon moves from one place and time A to another place and time B, the associated quantity is written in Feynman's shorthand as P(A text{ to } B). The similar quantity for an electron moving from C to D is written E(C text{ to } D). The quantity that tells us about the probability amplitude for the emission or absorption of a photon he calls j. This is related to, but not the same as, the measured electron charge e.{{rp|91}}QED is based on the assumption that complex interactions of many electrons and photons can be represented by fitting together a suitable collection of the above three building blocks and then using the probability amplitudes to calculate the probability of any such complex interaction. It turns out that the basic idea of QED can be communicated while assuming that the square of the total of the probability amplitudes mentioned above (P(A to B), E(C to D) and j) acts just like our everyday probability (a simplification made in Feynman's book). Later on, this will be corrected to include specifically quantum-style mathematics, following Feynman.The basic rules of probability amplitudes that will be used are:{{rp|93}}{{Ordered list|list_style_type = lower-alpha|If an event can happen in a variety of different ways, then its probability amplitude is the sum of the probability amplitudes of the possible ways.|If a process involves a number of independent sub-processes, then its probability amplitude is the product of the component probability amplitudes.}}## Basic constructionsSuppose, we start with one electron at a certain place and time (this place and time being given the arbitrary labelA) and a photon at another place and time (given the label B). A typical question from a physical standpoint is: "What is the probability of finding an electron at C (another place and a later time) and a photon at D (yet another place and time)?". The simplest process to achieve this end is for the electron to move from A to C (an elementary action) and for the photon to move from B to D (another elementary action). From a knowledge of the probability amplitudes of each of these sub-processes â€“ E(A to C) and P(B to D) â€“ we would expect to calculate the probability amplitude of both happening together by multiplying them, using rule b) above. This gives a simple estimated overall probability amplitude, which is squared to give an estimated probability.File:Compton Scattering.svg|thumb|left|200px|Compton scatteringCompton scatteringBut there are other ways in which the end result could come about. The electron might move to a place and time E, where it absorbs the photon; then move on before emitting another photon at F; then move on to C, where it is detected, while the new photon moves on to D. The probability of this complex process can again be calculated by knowing the probability amplitudes of each of the individual actions: three electron actions, two photon actions and two vertexes â€“ one emission and one absorption. We would expect to find the total probability amplitude by multiplying the probability amplitudes of each of the actions, for any chosen positions of E and F. We then, using rule a) above, have to add up all these probability amplitudes for all the alternatives for E and F. (This is not elementary in practice and involves integration.) But there is another possibility, which is that the electron first moves to G, where it emits a photon, which goes on to D, while the electron moves on to H, where it absorbs the first photon, before moving on to C. Again, we can calculate the probability amplitude of these possibilities (for all points G and H). We then have a better estimation for the total probability amplitude by adding the probability amplitudes of these two possibilities to our original simple estimate. Incidentally, the name given to this process of a photon interacting with an electron in this way is Compton scattering.There is an infinite number of other intermediate processes in which more and more photons are absorbed and/or emitted. For each of these possibilities, there is a Feynman diagram describing it. This implies a complex computation for the resulting probability amplitudes, but provided it is the case that the more complicated the diagram, the less it contributes to the result, it is only a matter of time and effort to find as accurate an answer as one wants to the original question. This is the basic approach of QED. To calculate the probability of any interactive process between electrons and photons, it is a matter of first noting, with Feynman diagrams, all the possible ways in which the process can be constructed from the three basic elements. Each diagram involves some calculation involving definite rules to find the associated probability amplitude.That basic scaffolding remains when one moves to a quantum description, but some conceptual changes are needed. One is that whereas we might expect in our everyday life that there would be some constraints on the points to which a particle can move, that is not true in full quantum electrodynamics. There is a possibility of an electron at A, or a photon at B, moving as a basic action to any other place and time in the universe. That includes places that could only be reached at speeds greater than that of light and also earlier times. (An electron moving backwards in time can be viewed as a positron moving forward in time.){{rp|89, 98â€“99}}## Probability amplitudes(File:Feynmans QED probability amplitudes.gif|frame|right|Feynman replaces complex numbers with spinning arrows, which start at emission and end at detection of a particle. The sum of all resulting arrows represents the total probability of the event. In this diagram, light emitted by the source bounces off a few segments of the mirror (in blue) before reaching the detector at S. The sum of all paths must be taken into account. The graph below depicts the total time spent to traverse each of the paths above.)Quantum mechanics introduces an important change in the way probabilities are computed. Probabilities are still represented by the usual real numbers we use for probabilities in our everyday world, but probabilities are computed as the square of probability amplitudes, which are complex numbers.Feynman avoids exposing the reader to the mathematics of complex numbers by using a simple but accurate representation of them as arrows on a piece of paper or screen. (These must not be confused with the arrows of Feynman diagrams, which are simplified representations in two dimensions of a relationship between points in three dimensions of space and one of time.) The amplitude arrows are fundamental to the description of the world given by quantum theory. They are related to our everyday ideas of probability by the simple rule that the probability of an event is the Psquare of the length of the corresponding amplitude arrow. So, for a given process, if two probability amplitudes, v and w, are involved, the probability of the process will be given either by
P = |mathbf{v} + mathbf{w}|^2
or
P = |mathbf{v} , mathbf{w}|^2.
The rules as regards adding or multiplying, however, are the same as above. But where you would expect to add or multiply probabilities, instead you add or multiply probability amplitudes that now are complex numbers.(File:AdditionComplexes.svg|thumb|right|200px|Addition of probability amplitudes as complex numbers)(File:MultiplicationComplexes.png|thumb|right|200px|Multiplication of probability amplitudes as complex numbers)Addition and multiplication are common operations in the theory of complex numbers and are given in the figures. The sum is found as follows. Let the start of the second arrow be at the end of the first. The sum is then a third arrow that goes directly from the beginning of the first to the end of the second. The product of two arrows is an arrow whose length is the product of the two lengths. The direction of the product is found by adding the angles that each of the two have been turned through relative to a reference direction: that gives the angle that the product is turned relative to the reference direction.That change, from probabilities to probability amplitudes, complicates the mathematics without changing the basic approach. But that change is still not quite enough because it fails to take into account the fact that both photons and electrons can be polarized, which is to say that their orientations in space and time have to be taken into account. Therefore, P(A to B) consists of 16 complex numbers, or probability amplitude arrows.{{rp|120â€“121}} There are also some minor changes to do with the quantity j, which may have to be rotated by a multiple of 90Â° for some polarizations, which is only of interest for the detailed bookkeeping.Associated with the fact that the electron can be polarized is another small necessary detail, which is connected with the fact that an electron is a fermion and obeys Fermiâ€“Dirac statistics. The basic rule is that if we have the probability amplitude for a given complex process involving more than one electron, then when we include (as we always must) the complementary Feynman diagram in which we exchange two electron events, the resulting amplitude is the reverse â€“ the negative â€“ of the first. The simplest case would be two electrons starting at A and B ending at C and D. The amplitude would be calculated as the "difference", {{nowrap|E(A to D) Ã— E(B to C) âˆ’ E(A to C) Ã— E(B to D)}}, where we would expect, from our everyday idea of probabilities, that it would be a sum.{{rp|112â€“113}}## PropagatorsFinally, one has to computeP(A to B) and E(C to D) corresponding to the probability amplitudes for the photon and the electron respectively. These are essentially the solutions of the Dirac equation, which describe the behavior of the electron's probability amplitude and the Maxwell's equations, which describes the behavior of the photon's probability amplitude. These are called Feynman propagators. The translation to a notation commonly used in the standard literature is as follows:
P(A text{ to } B) to D_F(x_B - x_A),quad E(C text{ to } D) to S_F(x_D - x_C),
where a shorthand symbol such as x_A stands for the four real numbers that give the time and position in three dimensions of the point labeled A.## Mass renormalizationFile:Electron self energy loop.svg|thumb|right|200px|Electron self-energyElectron self-energyA problem arose historically which held up progress for twenty years: although we start with the assumption of three basic "simple" actions, the rules of the game say that if we want to calculate the probability amplitude for an electron to get fromA to B, we must take into account all the possible ways: all possible Feynman diagrams with those endpoints. Thus there will be a way in which the electron travels to C, emits a photon there and then absorbs it again at D before moving on to B. Or it could do this kind of thing twice, or more. In short, we have a fractal-like situation in which if we look closely at a line, it breaks up into a collection of "simple" lines, each of which, if looked at closely, are in turn composed of "simple" lines, and so on ad infinitum. This is a challenging situation to handle. If adding that detail only altered things slightly, then it would not have been too bad, but disaster struck when it was found that the simple correction mentioned above led to infinite probability amplitudes. In time this problem was "fixed" by the technique of renormalization. However, Feynman himself remained unhappy about it, calling it a "dippy process".{{rp|128}}## ConclusionsWithin the above framework physicists were then able to calculate to a high degree of accuracy some of the properties of electrons, such as the anomalous magnetic dipole moment. However, as Feynman points out, it fails to explain why particles such as the electron have the masses they do. "There is no theory that adequately explains these numbers. We use the numbers in all our theories, but we don't understand them â€“ what they are, or where they come from. I believe that from a fundamental point of view, this is a very interesting and serious problem."{{rp|152}}## Mathematical formulationMathematically, QED is an abelian gauge theory with the symmetry group U(1). The gauge field, which mediates the interaction between the charged spin-1/2 fields, is the electromagnetic field.The QED Lagrangian for a spin-1/2 field interacting with the electromagnetic field is given in natural units by the real part ofBOOK, Peskin, Michael, Schroeder, Daniel, An introduction to quantum field theory, Westview Press, Reprint, 1995, 978-0201503975, {{rp|78}}{{Equation box 1|indent =:|equation = mathcal{L} = barpsi(igamma^mu D_mu - m)psi - frac{1}{4}F_{munu}F^{munu},|cellpadding|border|border colour = #50C878|background colour = #ECFCF4}}where
gamma^mu are Dirac matrices;
psi a bispinor field of spin-1/2 particles (e.g. electronâ€“positron field);
barpsiequivpsi^daggergamma^0, called "psi-bar", is sometimes referred to as the Dirac adjoint;
D_mu equiv partial_mu+ieA_mu+ieB_mu ,! is the gauge covariant derivative;
e is the coupling constant, equal to the electric charge of the bispinor field;
m is the mass of the electron or positron;
A_mu is the covariant four-potential of the electromagnetic field generated by the electron itself;
B_mu is the external field imposed by external source;
F_{munu} = partial_mu A_nu - partial_nu A_mu ,! is the electromagnetic field tensor.
## Equations of motionSubstituting the definition ofD into the Lagrangian gives
mathcal{L} = i barpsi gamma^mu partial_mu psi - ebar{psi}gamma^mu (A_mu+B_mu) psi -m bar{psi} psi - frac{1}{4}F_{munu}F^{munu}.
From this Lagrangian, the equations of motion for the Ïˆ and A fields can be obtained.Using the field-theoretic Eulerâ€“Lagrange equation for Ïˆ,{{NumBlk|:| partial_mu left( frac{partial mathcal{L}}{partial ( partial_mu psi )} right) - frac{partial mathcal{L}}{partial psi} = 0. | 2}}}}The derivatives of the Lagrangian concerning Ïˆ are
partial_mu left( frac{partial mathcal{L}}{partial ( partial_mu psi )} right) = partial_mu left( i bar{psi} gamma^mu right),
frac{partial mathcal{L}}{partial psi} = -ebar{psi}gamma^mu (A_mu+B_mu) - m bar{psi}.
Inserting these into ({{EquationNote|2}}) results in
i partial_mu bar{psi} gamma^mu + ebar{psi}gamma^mu (A_mu+B_mu) + m bar{psi} = 0,
with Hermitian conjugate
i gamma^mu partial_mu psi - e gamma^mu (A_mu+B_mu) psi - m psi = 0.
Bringing the middle term to the right-hand side yields{{Equation box 1|indent =:|equation = i gamma^mu partial_mu psi - m psi = e gamma^mu (A_mu+B_mu) psi.|cellpadding|border|border colour = #0073CF|background colour=#F5FFFA}}The left-hand side is like the original Dirac equation, and the right-hand side is the interaction with the electromagnetic field.Using the Eulerâ€“Lagrange equation for the A field,{{NumBlk|:| partial_nu left( frac{partial mathcal{L}}{partial ( partial_nu A_mu )} right) - frac{partial mathcal{L}}{partial A_mu} = 0,|{{EquationRef|3}}}}the derivatives this time are
partial_nu left( frac{partial mathcal{L}}{partial ( partial_nu A_mu )} right) = partial_nu left( partial^mu A^nu - partial^nu A^mu right),
frac{partial mathcal{L}}{partial A_mu} = -ebar{psi} gamma^mu psi.
Substituting back into ({{EquationNote|3}}) leads to{{Equation box 1|indent =:|equation = partial_nu F^{nu mu} = e bar{psi} gamma^mu psi.|cellpadding|border|border colour = #0073CF|background colour=#F5FFFA}}Now, if we impose the Lorenz gauge condition
partial_mu A^mu = 0,
the equations reduce to
Box A^mu = ebar{psi} gamma^mu psi,
which is a wave equation for the four-potential, the QED version of the classical Maxwell equations in the Lorenz gauge. (The square represents the D'Alembert operator, Box = partial_alpha partial^alpha.)## Interaction pictureThis theory can be straightforwardly quantized by treating bosonic and fermionic sectors{{clarify|reason=Definition needed.|date=April 2015}} as free. This permits us to build a set of asymptotic states that can be used to start computation of the probability amplitudes for different processes. In order to do so, we have to compute an evolution operator, which for a given initial state |irangle will give a final state langle f| in such a way to have{{rp|5}}
M_{fi} = langle f|U|irangle.
This technique is also known as the S-matrix. The evolution operator is obtained in the interaction picture, where time evolution is given by the interaction Hamiltonian, which is the integral over space of the second term in the Lagrangian density given above:{{rp|123}}
V = e int d^3 x, barpsi gamma^mu psi A_mu,
and so, one has{{rp|86}}
U = T expleft[-frac{i}{hbar} int_{t_0}^t dt', V(t')right],
where T is the time-ordering operator. This evolution operator only has meaning as a series, and what we get here is a perturbation series with the fine-structure constant as the development parameter. This series is called the Dyson series.## Feynman diagramsDespite the conceptual clarity of this Feynman approach to QED, almost no early textbooks follow him in their presentation. When performing calculations, it is much easier to work with the Fourier transforms of the propagators. Experimental tests of quantum electrodynamics are typically scattering experiments. In scattering theory, particles momenta rather than their positions are considered, and it is convenient to think of particles as being created or annihilated when they interact. Feynman diagrams thenlook the same, but the lines have different interpretations. The electron line represents an electron with a given energy and momentum, with a similar interpretation of the photon line. A vertex diagram represents the annihilation of one electron and the creation of another together with the absorption or creation of a photon, each having specified energies and momenta.Using Wick theorem on the terms of the Dyson series, all the terms of the S-matrix for quantum electrodynamics can be computed through the technique of Feynman diagrams. In this case, rules for drawing are the following{{rp|801â€“802}}missing image!
- qed rules.jpg -center missing image!
To these rules we must add a further one for closed loops that implies an integration on momenta int d^4p/(2pi)^4, since these internal ("virtual") particles are not constrained to any specific energyâ€“momentum, even that usually required by special relativity (see Propagator for details).From them, computations of probability amplitudes are straightforwardly given. An example is Compton scattering, with an electron and a photon undergoing elastic scattering. Feynman diagrams are in this case{{rp|158â€“159}}- qed2e.jpg -center missing image!
and so we are able to get the corresponding amplitude at the first order of a perturbation series for the S-matrix:
- compton qed.jpg -center
M_{fi} = (ie)^2 overline{u}(vec{p}', s')epsilon!!!/,'(vec{k}',lambda')^* frac{p!!!/ + k!!!/ + m_e}
{(p + k)^2 - m^2_e} epsilon!!!/(vec{k}, lambda) u(vec{p}, s) + (ie)^2overline{u}(vec{p}', s')epsilon!!!/(vec{k},lambda) frac{p!!!/ - k!!!/' + m_e}{(p - k')^2 - m^2_e} epsilon!!!/,'(vec{k}', lambda')^* u(vec{p}, s),from which we can compute the cross section for this scattering.## Nonperturbative phenomenaThe predictive success of quantum electrodynamics largely rests on the use of perturbation theory, expressed in Feynman diagrams. However, quantum electrodynamics also leads to predictions beyond perturbation theory. In the presence of very strong electric fields, it predicts that electrons and positrons will be spontaneously produced, so causing the decay of the field. This process, called the Schwinger effect,J. Schwinger, "On Gauge Invariance and Vacuum Polarization",Phys. Rev.,82 (1951) pp. 664â€“679. {{doi|10.1103/PhysRev.82.664}} cannot be understood in terms of any finite number of Feynman diagrams and hence is described as nonperturbative. Mathematically, it can be derived by a semiclassical approximation to the path integral of quantum electrodynamics.## RenormalizabilityHigher-order terms can be straightforwardly computed for the evolution operator, but these terms display diagrams containing the following simpler ones{{rp|ch 10}}Image:vacuum_polarization.svg | One-loop contribution to the vacuum polarization function PiImage:electron_self_energy.svg | One-loop contribution to the electron self-energy function SigmaImage:vertex_correction.svg | One-loop contribution to the vertex function Gammathat, being closed loops, imply the presence of diverging integrals having no mathematical meaning. To overcome this difficulty, a technique called renormalization has been devised, producing finite results in very close agreement with experiments. A criterion for the theory being meaningful after renormalization is that the number of diverging diagrams is finite. In this case, the theory is said to be "renormalizable". The reason for this is that to get observables renormalized, one needs a finite number of constants to maintain the predictive value of the theory untouched. This is exactly the case of quantum electrodynamics displaying just three diverging diagrams. This procedure gives observables in very close agreement with experiment as seen e.g. for electron gyromagnetic ratio.Renormalizability has become an essential criterion for a quantum field theory to be considered as a viable one. All the theories describing fundamental interactions, except gravitation, whose quantum counterpart is presently under very active research, are renormalizable theories.## Nonconvergence of seriesAn argument by Freeman Dyson shows that the radius of convergence of the perturbation series in QED is zero.WEB, Kinoshita , The basic argument goes as follows: if the coupling constant were negative, this would be equivalent to the Coulomb force constant being negative. This would "reverse" the electromagnetic interaction so that , Toichiro , Quantum Electrodynamics has Zero Radius of Convergence Summarized from Toichiro Kinoshita , , June 5, 1997 ,weblink , May 6, 2017 like charges would attract and unlike charges would repel. This would render the vacuum unstable against decay into a cluster of electrons on one side of the universe and a cluster of positrons on the other side of the universe. Because the theory is "sick" for any negative value of the coupling constant, the series does not converge but are at best an asymptotic series.From a modern perspective, we say that QED is not well defined as a quantum field theory to arbitrarily high energy.JOURNAL
, Espriu and Tarrach
, Ambiguities in QED: Renormalons versus Triviality , Apr 30, 1996 , hep-ph/9604431 , 10.1016/0370-2693(96)00779-4 , 383 , 4 , Physics Letters B , 482â€“486, 1996PhLB..383..482E, The coupling constant runs to infinity at finite energy, signalling a Landau pole. The problem is essentially that QED appears to suffer from quantum triviality issues. This is one of the motivations for embedding QED within a Grand Unified Theory. ## See also{{Div col|colwidth=20em|small=yes}}- Abrahamâ€“Lorentz force
- Anomalous magnetic moment
- Basics of quantum mechanics
- Bhabha scattering
- Cavity quantum electrodynamics
- Compton scattering
- Eulerâ€“Heisenberg Lagrangian
- Feynman path integrals
- Gauge theory
- Guptaâ€“Bleuler formalism
- Lamb shift
- Landau pole
- Moeller scattering
- Photon polarization
- Positronium
- Precision tests of QED
- Propagators
- QED vacuum
- Quantum chromodynamics
- Quantum field theory
- Quantum gauge theory
- Renormalization
- Scalar electrodynamics
- SchrÃ¶dinger equation
- Schwinger model
- Schwinger-Dyson equation
- Self-energy
- Standard Model
- Symmetry in quantum mechanics
- Theoretical and experimental justification for the SchrÃ¶dinger equation
- Vacuum polarization
- Vertex function
- Wardâ€“Takahashi identity
- Wheelerâ€“Feynman absorber theory
## References{{Reflist|30em}}## Further reading## Books- BOOK, De Broglie, Louis, Louis de Broglie, Recherches sur la theorie des quanta [Research on quantum theory], 1925, Wiley-Interscience, France,
- BOOK, Feynman, Richard Phillips, Richard Feynman, Quantum Electrodynamics, 1998, Westview Press, New, 978-0-201-36075-2,
- BOOK, Jauch, J.M., Rohrlich, F., The Theory of Photons and Electrons, 1980, Springer-Verlag, 978-0-387-07295-1,
- BOOK, Greiner, Walter, Bromley, D.A., MÃ¼ller, Berndt, Gauge Theory of Weak Interactions, 2000, Springer, 978-3-540-67672-0,
- BOOK, Kane, Gordon, L., Modern Elementary Particle Physics, 1993, Westview Press, 978-0-201-62460-1,
- BOOK, Miller, Arthur I., Early Quantum Electrodynamics: A Sourcebook, 1995, Cambridge University Press, 978-0-521-56891-3,
- BOOK, Milonni, Peter W., Peter W. Milonni, The Quantum Vacuum: An Introduction to Quantum Electrodynamics, 1994, Academic Press, Boston, 0124980805,weblink 93029780, 422797902, harv,
- BOOK, Schweber, Silvan S., QED and the Men Who Made It, 1994, Princeton University Press, 978-0-691-03327-3,
- BOOK, Schwinger, Julian, Julian Schwinger, Selected Papers on Quantum Electrodynamics, 1958, Dover Publications, 978-0-486-60444-2,
- BOOK, Tannoudji-Cohen, Claude, Claude Cohen-Tannoudji, Dupont-Roc, Jacques, Grynberg, Gilbert, Photons and Atoms: Introduction to Quantum Electrodynamics, 1997, Wiley-Interscience, 978-0-471-18433-1,
## Journals- JOURNAL, Dudley, J.M., Kwan, A.M., 1996, Richard Feynman's popular lectures on quantum electrodynamics: The 1979 Robb Lectures at Auckland University, American Journal of Physics, 64, 6, 694â€“98, 10.1119/1.18234, 1996AmJPh..64..694D,
## External links{{-}}{{QED}}{{Quantum field theories}}{{Standard model of physics}}{{Branches of physics}}{{Authority control}}{{Good article}} |

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