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Sodium
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{{about|the chemical element|the nutrient commonly called sodium|salt|other uses|sodium (disambiguation)}}{{redirect|Natrium}}{{short description|Chemical element with atomic number 11}}







factoids
Sodium is a chemical element with the symbol Na (from Latin natrium) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table, because it has a single electron in its outer shell, which it readily donates, creating a positively charged ion—the Na+ cation. Its only stable isotope is 23Na. The free metal does not occur in nature, and must be prepared from compounds. Sodium is the sixth most abundant element in the Earth's crust and exists in numerous minerals such as feldspars, sodalite, and rock salt (NaCl). Many salts of sodium are highly water-soluble: sodium ions have been leached by the action of water from the Earth's minerals over eons, and thus sodium and chlorine are the most common dissolved elements by weight in the oceans.Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful sodium compounds, sodium hydroxide (lye) is used in soap manufacture, and sodium chloride (edible salt) is a de-icing agent and a nutrient for animals including humans.Sodium is an essential element for all animals and some plants. Sodium ions are the major cation in the extracellular fluid (ECF) and as such are the major contributor to the ECF osmotic pressure and ECF compartment volume. Loss of water from the ECF compartment increases the sodium concentration, a condition called hypernatremia. Isotonic loss of water and sodium from the ECF compartment decreases the size of that compartment in a condition called ECF hypovolemia.By means of the sodium-potassium pump, living human cells pump three sodium ions out of the cell in exchange for two potassium ions pumped in; comparing ion concentrations across the cell membrane, inside to outside, potassium measures about 40:1, and sodium, about 1:10. In nerve cells, the electrical charge across the cell membrane enables transmission of the nerve impulse—an action potential—when the charge is dissipated; sodium plays a key role in that activity.

Characteristics

Physical

File:Na-D-sodium D-lines-589nm.jpg|thumb|left|Emission spectrum for sodium, showing the D line.]]Sodium at standard temperature and pressure is a soft silvery metal that combines with oxygen in the air and forms grayish white sodium oxide unless immersed in oil or inert gas, which are the conditions it is usually stored in. Sodium metal can be easily cut with a knife and is a good conductor of electricity and heat because it has only one electron in its valence shell, resulting in weak metallic bonding and free electrons, which carry energy. Due to having low atomic mass and large atomic radius, sodium is third-least dense of all elemental metals and is one of only three metals that can float on water, the other two being lithium and potassium.Greenwood and Earnshaw, p. 75 The melting (98 Â°C) and boiling (883 Â°C) points of sodium are lower than those of lithium but higher than those of the heavier alkali metals potassium, rubidium, and caesium, following periodic trends down the group.WEB,weblink "Alkali Metals." Science of Everyday Things, Encyclopedia.com, 15 October 2016, These properties change dramatically at elevated pressures: at 1.5 Mbar, the color changes from silvery metallic to black; at 1.9 Mbar the material becomes transparent with a red color; and at 3 Mbar, sodium is a clear and transparent solid. All of these high-pressure allotropes are insulators and electrides.JOURNAL, Gatti, M., Tokatly, I., Rubio, A., 2010, Sodium: A Charge-Transfer Insulator at High Pressures, Physical Review Letters, 104, 21, 216404, 20867123, 10.1103/PhysRevLett.104.216404, 2010PhRvL.104u6404G, 1003.0540, File:Flametest--Na.swn.jpg|thumb|left|upright|A positive flame testflame testIn a flame test, sodium and its compounds glow yellowBOOK, Schumann, Walter, Minerals of the World, 5 August 2008, Sterling, 978-1-4027-5339-8, 2nd, 28, 637302667, because the excited 3s electrons of sodium emit a photon when they fall from 3p to 3s; the wavelength of this photon corresponds to the D line at about 589.3 nm. Spin-orbit interactions involving the electron in the 3p orbital split the D line into two, at 589.0 and 589.6 nm; hyperfine structures involving both orbitals cause many more lines.JOURNAL, Citron, M. L., Gabel, C., Stroud, C., 1977, Experimental Study of Power Broadening in a Two-Level Atom, Physical Review A, 16, 10.1103/PhysRevA.16.1507, 1507–1512, 4, 1977PhRvA..16.1507C, Stroud, C.,

Isotopes

Twenty isotopes of sodium are known, but only 23Na is stable. 23Na is created in the carbon-burning process in stars by fusing two carbon atoms together; this requires temperatures above 600 megakelvins and a star of at least three solar masses.JOURNAL, 1987SvAL...13..214D, Sodium Synthesis in Hydrogen Burning Stars, Denisenkov, P. A., Ivanov, V. V., 13, 1987, 214, Soviet Astronomy Letters, Two radioactive, cosmogenic isotopes are the byproduct of cosmic ray spallation: 22Na has a half-life of 2.6 years and 24Na, a half-life of 15 hours; all other isotopes have a half-life of less than one minute.{{NUBASE 2003}} Two nuclear isomers have been discovered, the longer-lived one being 24mNa with a half-life of around 20.2 milliseconds. Acute neutron radiation, as from a nuclear criticality accident, converts some of the stable 23Na in human blood to 24Na; the neutron radiation dosage of a victim can be calculated by measuring the concentration of 24Na relative to 23Na.JOURNAL, Neutron Activation of Sodium in Anthropomorphous Phantoms, Health Physics, 8, 4, 371–379, 1962, Sanders, F. W., Auxier, J. A., 10.1097/00004032-196208000-00005, 14496815,

Chemistry

Sodium atoms have 11 electrons, one more than the extremely stable configuration of the noble gas neon. Because of this and its low first ionization energy of 495.8 kJ/mol, the sodium atom is much more likely to lose the last electron and acquire a positive charge than to gain one and acquire a negative charge. This process requires so little energy that sodium is readily oxidized by giving up its 11th electron. In contrast, the second ionization energy is very high (4562 kJ/mol), because the 10th electron is closer to the nucleus than the 11th electron. As a result, sodium usually forms ionic compounds involving the Na+ cation.BOOK, Cambridge International AS and A Level Chemistry Coursebook, Lawrie Ryan, Roger Norris, Cambridge University Press, 2014, illustrated, 978-1-107-63845-7, 36, 2014-07-31, The most common oxidation state for sodium is +1. It is generally less reactive than potassium and more reactive than lithium.WEB, De Leon, N., Reactivity of Alkali Metals,weblink Indiana University Northwest, 2007-12-07, Sodium metal is highly reducing, with the standard reduction potential for the Na+/Na couple being −2.71 volts,BOOK, Atkins, Peter W., de Paula, Julio, Physical Chemistry, 2002, 7th, W. H. Freeman, 978-0-7167-3539-7, 3345182,weblink though potassium and lithium have even more negative potentials.BOOK, Davies, Julian A., Synthetic Coordination Chemistry: Principles and Practice, 1996, World Scientific, 978-981-02-2084-6, 717012347, 293,

Salts and oxides

{{Category see also|Sodium compounds}}File:NaCl polyhedra.png|thumb|left|220 px|Structure of sodium chloridesodium chlorideSodium compounds are of immense commercial importance, being particularly central to industries producing glass, paper, soap, and textiles. The most important sodium compounds are table salt (NaCl), soda ash (Na2CO3), baking soda (NaHCO3), caustic soda (NaOH), sodium nitrate (NaNO3), di- and tri-sodium phosphates, sodium thiosulfate (Na2S2O3·5H2O), and borax (Na2B4O7·10H2O). In compounds, sodium is usually ionically bonded to water and anions and is viewed as a hard Lewis acid.BOOK, Cowan, James A., Inorganic Biochemistry: An Introduction, 1997, Wiley-VCH, 978-0-471-18895-7, 7, 34515430, File:SodiumSterateChemStr.png|thumb|center|upright=1.4|Two equivalent images of the chemical structure of sodium stearatesodium stearateMost soaps are sodium salts of fatty acids. Sodium soaps have a higher melting temperature (and seem "harder") than potassium soaps.BOOK, Walter de Gruyter, 1985, 91–100, 931–943, 978-3-11-007511-3, Lehrbuch der Anorganischen Chemie, Holleman, Arnold F., Wiberg, Egon, Wiberg, Nils, German, Like all the alkali metals, sodium reacts exothermically with water, and sufficiently large pieces melt to a sphere and may explode. The reaction produces caustic soda (sodium hydroxide) and flammable hydrogen gas. When burned in air, it forms primarily sodium peroxide with some sodium oxide.Greenwoood and Earnshaw, p. 84

Aqueous solutions

Sodium tends to form water-soluble compounds, such as halides, sulfates, nitrates, carboxylates and carbonates. The main aqueous species are the aquo complexes [Na(H2O)n]+, where n = 4–8; with n = 6 indicated from X-ray diffraction data and computer simulations.BOOK, 10.1016/B0-08-043748-6/01055-0, Comprehensive Coordination Chemistry II, 2004, 978-0-08-043748-4, 515, Metal Aqua Ions, Lincoln, S. F., Richens, D. T., Sykes, A. G., Direct precipitation of sodium salts from aqueous solutions is rare because sodium salts typically have a high affinity for water; an exception is sodium bismuthate (NaBiO3).BOOK, Lange's Handbook of Chemistry, McGraw-Hill, 1998, 978-0-07-016384-3, Dean, John Aurie, Lange, Norbert Adolph, Because of this, sodium salts are usually isolated as solids by evaporation or by precipitation with an organic solvent, such as ethanol; for example, only 0.35 g/L of sodium chloride will dissolve in ethanol.BOOK, Burgess, J., Metal Ions in Solution, Ellis Horwood, New York, 1978, 978-0-85312-027-8, Crown ethers, like 15-crown-5, may be used as a phase-transfer catalyst.BOOK, Starks, Charles M., Liotta, Charles L., Halpern, Marc, Phase-Transfer Catalysis: Fundamentals, Applications, and Industrial Perspectives, 1994, Chapman & Hall, 162, 978-0-412-04071-9, 28027599, Sodium content in bulk may be determined by treating with a large excess of uranyl zinc acetate; the hexahydrate (UO2)3ZnNa(CH3CO2)9·6H2O precipitates and can be weighed. Caesium and rubidium do not interfere with this reaction, but potassium and lithium do.JOURNAL, J. Am. Chem. Soc., 10.1021/ja01386a008, 1929, Barber, H. H., Kolthoff, I. M., 51, 11, 3233–3237, Gravimetric Determination of Sodium by the Uranyl Zinc Acetate Method. Ii. Application in the Presence of Rubidium, Cesium, Potassium, Lithium, Phosphate or Arsenate, Lower concentrations of sodium may be determined by atomic absorption spectrophotometryJOURNAL,weblink J. Biol. Chem., 206, 2, 807–15, 1954, 13143043, Kingsley, G. R., Schaffert, R. R., Micro-flame Photometric Determination of Sodium, Potassium and Calcium in Serum with Solvents, or by potentiometry using ion-selective electrodes.JOURNAL, Levy, G. B., Determination of Sodium with Ion-Selective Electrodes, Clinical Chemistry,weblink 27, 8, 1435–1438, 1981, 7273405,

Electrides and sodides

Like the other alkali metals, sodium dissolves in ammonia and some amines to give deeply colored solutions; evaporation of these solutions leaves a shiny film of metallic sodium. The solutions contain the coordination complex (Na(NH3)6)+, with the positive charge counterbalanced by electrons as anions; cryptands permit the isolation of these complexes as crystalline solids. Sodium forms complexes with crown ethers, cryptands and other ligands.BOOK, Applications of the Newer Techniques of Analysis, Ivor L. Simmons, Springer Science & Business Media, 2012, 978-1-4684-3318-0, 160, For example, 15-crown-5 has a high affinity for sodium because the cavity size of 15-crown-5 is 1.7–2.2 Ã…, which is enough to fit the sodium ion (1.9 Ã…).BOOK, Design, Fabrication, Properties and Applications of Smart and Advanced Materials, Xu Hou, CRC Press, 2016, illustrated, 978-1-4987-2249-0, 175, 2016-06-22, BOOK, Anionic Polymerization: Principles, Practice, Strength, Consequences and Applications, Nikos Hadjichristidis, Akira Hirao, Springer, 2015, illustrated, 978-4-431-54186-8, 349, 2015-09-01, Cryptands, like crown ethers and other ionophores, also have a high affinity for the sodium ion; derivatives of the alkalide Na− are obtainableJOURNAL, J. Am. Chem. Soc., Dye, J. L., Ceraso, J. M., Mei Lok Tak, Barnett, B. L., Tehan, F. J., Crystalline Salt of the Sodium Anion (Na−), 1974, 96, 2, 608–609, 10.1021/ja00809a060, by the addition of cryptands to solutions of sodium in ammonia via disproportionation.BOOK, Holleman, A. F., Wiberg, E., Wiberg, N., Inorganic Chemistry, Academic Press, 2001, 978-0-12-352651-9, 48056955,

Organosodium compounds

File:Monensin2.png|thumb|The structure of the complex of sodium (Na+, shown in yellow) and the antibiotic monensinmonensinMany organosodium compounds have been prepared. Because of the high polarity of the C-Na bonds, they behave like sources of carbanions (salts with organic anions). Some well-known derivatives include sodium cyclopentadienide (NaC5H5) and trityl sodium ((C6H5)3CNa).{{OrgSynth |first1=W. B. | last1=Renfrow, Jr. |first2=C. R. | last2= Hauser |year=1943 |title=Triphenylmethylsodium |volume= |pages= |collvol=2 |collvolpages=607 |prep=CV2P0607}} Because of the large size and very low polarising power of the Na+ cation, it can stabilize large, aromatic, polarisable radical anions, such as in sodium naphthalenide, Na+[C10H8•]−, a strong reducing agent.Greenwood and Earnshaw, p. 111

Intermetallic compounds

Sodium forms alloys with many metals, such as potassium, calcium, lead, and the group 11 and 12 elements. Sodium and potassium form KNa2 and NaK. NaK is 40–90% potassium and it is liquid at ambient temperature. It is an excellent thermal and electrical conductor. Sodium-calcium alloys are by-products of the electrolytic production of sodium from a binary salt mixture of NaCl-CaCl2 and ternary mixture NaCl-CaCl2-BaCl2. Calcium is only partially miscible with sodium. In a liquid state, sodium is completely miscible with lead. There are several methods to make sodium-lead alloys. One is to melt them together and another is to deposit sodium electrolytically on molten lead cathodes. NaPb3, NaPb, Na9Pb4, Na5Pb2, and Na15Pb4 are some of the known sodium-lead alloys. Sodium also forms alloys with gold (NaAu2) and silver (NaAg2). Group 12 metals (zinc, cadmium and mercury) are known to make alloys with sodium. NaZn13 and NaCd2 are alloys of zinc and cadmium. Sodium and mercury form NaHg, NaHg4, NaHg2, Na3Hg2, and Na3Hg.BOOK, Alloys: Preparation, Properties, Applications, Habashi, Fathi, John Wiley & Sons, 2008, 978-3-527-61192-8, 278–280, 2008-11-21,

History

Because of its importance in human metabolism, salt has long been an important commodity, as shown by the English word salary, which derives from salarium, the wafers of salt sometimes given to Roman soldiers along with their other wages. In medieval Europe, a compound of sodium with the Latin name of sodanum was used as a headache remedy. The name sodium is thought to originate from the Arabic suda, meaning headache, as the headache-alleviating properties of sodium carbonate or soda were well known in early times.BOOK, Newton, David E., Baker, Lawrence W., Chemical Elements, 1999, 978-0-7876-2847-5, 39778687,weblink Although sodium, sometimes called soda, had long been recognized in compounds, the metal itself was not isolated until 1807 by Sir Humphry Davy through the electrolysis of sodium hydroxide.JOURNAL, Humphry, Davy, On some new phenomena of chemical changes produced by electricity, particularly the decomposition of the fixed alkalies, and the exhibition of the new substances which constitute their bases; and on the general nature of alkaline bodies, 1808, 98, Philosophical Transactions of the Royal Society of London, 1–44,weblink 10.1098/rstl.1808.0001, JOURNAL, 10.1021/ed009p1035, The discovery of the elements. IX. Three alkali metals: Potassium, sodium, and lithium, 1932, Weeks, Mary Elvira, Mary Elvira Weeks, Journal of Chemical Education, 9, 6, 1035, 1932JChEd...9.1035W, In 1809, the German physicist and chemist Ludwig Wilhelm Gilbert proposed the names Natronium for Humphry Davy's "sodium" and Kalium for Davy's "potassium".Humphry Davy (1809) "Ueber einige neue Erscheinungen chemischer Veränderungen, welche durch die Electricität bewirkt werden; insbesondere über die Zersetzung der feuerbeständigen Alkalien, die Darstellung der neuen Körper, welche ihre Basen ausmachen, und die Natur der Alkalien überhaupt" (On some new phenomena of chemical changes that are achieved by electricity; particularly the decomposition of flame-resistant alkalis [i.e., alkalies that cannot be reduced to their base metals by flames], the preparation of new substances that constitute their [metallic] bases, and the nature of alkalies generally), Annalen der Physik, 31 (2) : 113–175 ; see footnote p. 157. From p. 157: "In unserer deutschen Nomenclatur würde ich die Namen Kalium und Natronium vorschlagen, wenn man nicht lieber bei den von Herrn Erman gebrauchten und von mehreren angenommenen Benennungen Kali-Metalloid and Natron-Metalloid, bis zur völligen Aufklärung der chemischen Natur dieser räthzelhaften Körper bleiben will. Oder vielleicht findet man es noch zweckmässiger fürs Erste zwei Klassen zu machen, Metalle und Metalloide, und in die letztere Kalium und Natronium zu setzen. — Gilbert." (In our German nomenclature, I would suggest the names Kalium and Natronium, if one would not rather continue with the appellations Kali-metalloid and Natron-metalloid which are used by Mr. Erman and accepted by several [people], until the complete clarification of the chemical nature of these puzzling substances. Or perhaps one finds it yet more advisable for the present to create two classes, metals and metalloids, and to place Kalium and Natronium in the latter — Gilbert.) The chemical abbreviation for sodium was first published in 1814 by Jöns Jakob Berzelius in his system of atomic symbols,J. Jacob Berzelius, Försök, att, genom användandet af den electrokemiska theorien och de kemiska proportionerna, grundlägga ett rent vettenskapligt system för mineralogien [Attempt, by the use of electrochemical theory and chemical proportions, to found a pure scientific system for mineralogy] (Stockholm, Sweden: A. Gadelius, 1814), p. 87.WEB,weblink Elementymology & Elements Multidict, Peter, van der Krogt, 2007-06-08, and is an abbreviation of the element's New Latin name natrium, which refers to the Egyptian natron, a natural mineral salt mainly consisting of hydrated sodium carbonate. Natron historically had several important industrial and household uses, later eclipsed by other sodium compounds.JOURNAL, Natron as a flux in the early vitreous materials industry: sources, beginnings and reasons for decline, Andrew Shortland, Lukas Schachner, Ian Freestone, and Michael Tite, 10.1016/j.jas.2005.09.011, 33, 4, Journal of Archaeological Science, 521–530, 2006, Sodium imparts an intense yellow color to flames. As early as 1860, Kirchhoff and Bunsen noted the high sensitivity of a sodium flame test, and stated in Annalen der Physik und Chemie:JOURNAL, 10.1002/andp.18601860602, Chemische Analyse durch Spectralbeobachtungen, 1860, Kirchhoff, G., Bunsen, R., Annalen der Physik und Chemie, 186, 6, 161–189, 1860AnP...186..161K,weblink In a corner of our 60 m3 room farthest away from the apparatus, we exploded 3 mg of sodium chlorate with milk sugar while observing the nonluminous flame before the slit. After a while, it glowed a bright yellow and showed a strong sodium line that disappeared only after 10 minutes. From the weight of the sodium salt and the volume of air in the room, we easily calculate that one part by weight of air could not contain more than 1/20 millionth weight of sodium.

Occurrence

The Earth's crust contains 2.27% sodium, making it the seventh most abundant element on Earth and the fifth most abundant metal, behind aluminium, iron, calcium, and magnesium and ahead of potassium.Greenwood and Earnshaw, p. 69 Sodium's estimated oceanic abundance is 1.08{{e|4}} milligrams per liter.BOOK,weblink CRC Handbook of Chemistry and Physics, 84th Edition, Lide, David R., 2003-06-19, CRC Press, 978-0-8493-0484-2, CRC Handbook, 14: Abundance of Elements in the Earth's Crust and in the Sea, en, Because of its high reactivity, it is never found as a pure element. It is found in many different minerals, some very soluble, such as halite and natron, others much less soluble, such as amphibole and zeolite. The insolubility of certain sodium minerals such as cryolite and feldspar arises from their polymeric anions, which in the case of feldspar is a polysilicate.

Astronomical observations

Atomic sodium has a very strong spectral line in the yellow-orange part of the spectrum (the same line as is used in sodium vapour street lights). This appears as an absorption line in many types of stars, including the Sun. The line was first studied in 1814 by Joseph von Fraunhofer during his investigation of the lines in the solar spectrum, now known as the Fraunhofer lines. Fraunhofer named it the 'D line', although it is now known to actually be a group of closely spaced lines split by a fine and hyperfine structure.WEB, D-lines {{!, spectroscopy|url=https://www.britannica.com/topic/D-lines|website=Encyclopedia Britannica|accessdate=6 November 2017|language=en}}The strength of the D line means it has been detected in many other astronomical environments. In stars, it is seen in any whose surfaces are cool enough for sodium to exist in atomic form (rather than ionised). This corresponds to stars of roughly F-type and cooler. Many other stars appear to have a sodium absorption line, but this is actually caused by gas in the foreground interstellar medium. The two can be distinguished via high-resolution spectroscopy, because interstellar lines are much narrower than those broadened by stellar rotation.JOURNAL, 1994ApJ...436..152W, 10.1086/174889, A high-resolution survey of interstellar NA I D1 lines, The Astrophysical Journal, 436, 152, 1994, Welty, Daniel E, Hobbs, L. M, Kulkarni, Varsha P, Sodium has also been detected in numerous Solar System environments, including Mercury's atmosphere,{{citation needed|date=March 2017}} the exosphere of the Moon,JOURNAL, 2016Sci...351..249C, 10.1126/science.aad2380, 26678876, How surface composition and meteoroid impacts mediate sodium and potassium in the lunar exosphere, Science, 351, 6270, 249–52, 2015, Colaprete, A, Sarantos, M, Wooden, D. H, Stubbs, T. J, Cook, A. M, Shirley, M, and numerous other bodies. Some comets have a sodium tail,WEB, Cometary Neutral Tail {{!, COSMOS|url=http://astronomy.swin.edu.au/cosmos/C/Cometary+Neutral+Tail|website=astronomy.swin.edu.au|accessdate=6 November 2017|language=en}} which was first detected in observations of Comet Hale-Bopp in 1997.JOURNAL, The Astrophysical Journal Letters, 490, 2, L199–L202, 1997, 10.1086/311040, Neutral Sodium from Comet Hale–Bopp: A Third Type of Tail, Cremonese, G, Boehnhardt, H, Crovisier, J, Rauer, H, Fitzsimmons, A, Fulle, M, Licandro, J, Pollacco, D, Tozzi, G. P, 1997ApJ...490L.199C, astro-ph/9710022, 8, West, R. M., Sodium has even been detected in the atmospheres of some extrasolar planets via transit spectroscopy.JOURNAL, 2008ApJ...673L..87R, 10.1086/527475, Sodium Absorption from the Exoplanetary Atmosphere of HD 189733b Detected in the Optical Transmission Spectrum, The Astrophysical Journal, 673, 1, L87–L90, 2008, Redfield, Seth, Endl, Michael, Cochran, William D, Koesterke, Lars, 0712.0761,

Commercial production

Employed only in rather specialized applications, only about 100,000 tonnes of metallic sodium are produced annually. Metallic sodium was first produced commercially in the late 19th centuryBOOK, Speciality Chemicals: Innovations in industrial synthesis and applications, Springer Science & Business Media, 1991, B. Pearson, 978-1-85166-646-1, 260, illustrated, 1991-12-31, by carbothermal reduction of sodium carbonate at 1100 Â°C, as the first step of the Deville process for the production of aluminium:BOOK, Eggeman, Tim, Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, 2007, 10.1002/0471238961.1915040912051311.a01.pub3, Updated By Staff, 978-0-471-23896-6, Sodium and Sodium Alloys, JOURNAL, 27757153, 205–221, Oesper, R. E., Lemay, P., Henri Sainte-Claire Deville, 1818–1881, 3, Chymia, 1950, 10.2307/27757153, JOURNAL, 10.1021/ed067p1046, Sodium, 1990, Banks, Alton, Journal of Chemical Education, 67, 12, 1046, 1990JChEd..67.1046B,
Na2CO3 + 2 C → 2 Na + 3 CO
The high demand for aluminium created the need for the production of sodium. The introduction of the Hall–Héroult process for the production of aluminium by electrolysing a molten salt bath ended the need for large quantities of sodium. A related process based on the reduction of sodium hydroxide was developed in 1886.Sodium is now produced commercially through the electrolysis of molten sodium chloride, based on a process patented in 1924.Pauling, Linus, General Chemistry, 1970 ed., Dover PublicationsWEB,weblink Los Alamos National Laboratory – Sodium, 2007-06-08, This is done in a Downs cell in which the NaCl is mixed with calcium chloride to lower the melting point below 700 Â°C. As calcium is less electropositive than sodium, no calcium will be deposited at the cathode.BOOK, Sodium Metal from France, DIANE Publishing, 978-1-4578-1780-9, This method is less expensive than the previous Castner process (the electrolysis of sodium hydroxide).BOOK, Industrial Chemistry: For Advanced Students, Mark Anthony Benvenuto, Walter de Gruyter GmbH & Co KG, 2015, illustrated, 978-3-11-038339-3, 2015-02-24, The market for sodium is volatile due to the difficulty in its storage and shipping; it must be stored under a dry inert gas atmosphere or anhydrous mineral oil to prevent the formation of a surface layer of sodium oxide or sodium superoxide.BOOK, Active Pharmaceutical Ingredients: Development, Manufacturing, and Regulation, Second Edition, CRC Press, 2016, 978-1-4398-0339-4, Stanley Nusim, 2, illustrated, revised, 303, 2016-04-19,

Uses

{{see also|Sodium supplements}}Though metallic sodium has some important uses, the major applications for sodium use compounds; millions of tons of sodium chloride, hydroxide, and carbonate are produced annually. Sodium chloride is extensively used for anti-icing and de-icing and as a preservative; examples of the uses of sodium bicarbonate include baking, as a raising agent, and sodablasting. Along with potassium, many important medicines have sodium added to improve their bioavailability; though potassium is the better ion in most cases, sodium is chosen for its lower price and atomic weight.BOOK, Remington, Joseph P., Remington: The Science and Practice of Pharmacy, 2006, Lippincott Williams & Wilkins, 978-0-7817-4673-1, 365–366, 21st, Beringer, Paul, 60679584, Sodium hydride is used as a base for various reactions (such as the aldol reaction) in organic chemistry, and as a reducing agent in inorganic chemistry.BOOK, Wiberg, Egon, Wiberg, Nils, Holleman, A. F., Inorganic Chemistry, 2001, Academic Press, 1103–1104,weblink 978-0-12-352651-9, 48056955, Metallic sodium is used mainly for the production of sodium borohydride, sodium azide, indigo, and triphenylphosphine. A once-common use was the making of tetraethyllead and titanium metal; because of the move away from TEL and new titanium production methods, the production of sodium declined after 1970.Alfred Klemm, Gabriele Hartmann, Ludwig Lange, "Sodium and Sodium Alloys" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH, Weinheim. {{DOI|10.1002/14356007.a24_277}} Sodium is also used as an alloying metal, an anti-scaling agent,BOOK,weblink 76, Metal cleaning: bibliographical abstracts, 1842–1951, Harris, Jay C., 1949, American Society for Testing and Materials, 1848092, and as a reducing agent for metals when other materials are ineffective. Note the free element is not used as a scaling agent, ions in the water are exchanged for sodium ions. Sodium plasma ("vapor") lamps are often used for street lighting in cities, shedding light that ranges from yellow-orange to peach as the pressure increases.BOOK,weblink 112–114, Applied illumination engineering, Lindsey, Jack L., 1997, Fairmont Press, 978-0-88173-212-2, 22184876, By itself or with potassium, sodium is a desiccant; it gives an intense blue coloration with benzophenone when the desiccate is dry.BOOK, Lerner, Leonid, Small-Scale Synthesis of Laboratory Reagents with Reaction Modeling,weblink 91–92, 2011-02-16, CRC Press, 978-1-4398-1312-6, 669160695, In organic synthesis, sodium is used in various reactions such as the Birch reduction, and the sodium fusion test is conducted to qualitatively analyse compounds.BOOK, Sethi, Arun, Systematic Laboratory Experiments in Organic Chemistry,weblink 32–35, New Age International, 978-81-224-1491-2, 86068991, 1 January 2006, Sodium reacts with alcohol and gives alkoxides, and when sodium is dissolved in ammonia solution, it can be used to reduce alkynes to trans-alkenes.BOOK, Organic Synthesis, Smith, Michael, Academic Press, 2011, 3, 978-0-12-415884-9, 455, 2011-07-12, BOOK, Organic Chemistry, Solomons, Fryhle, John Wiley & Sons, 2006, 8, 978-81-265-1050-4, 272, 2006, Lasers emitting light at the sodium D line are used to create artificial laser guide stars that assist in the adaptive optics for land-based visible-light telescopes.WEB,weblink Domenico Bonaccini Calia, Yan Feng, Wolfgang Hackenberg, Ronald Holzlöhner, Luke Taylor, Steffan Lewis, Laser Development for Sodium Laser Guide Stars at ESO,

Heat transfer

File:Phase diagram potassium sodium s l.svg|upright=1.8|thumb|NaK phase diagram, showing the melting point of sodium as a function of potassium concentration. NaK with 77% potassium is eutectic and has the lowest melting point of the NaK alloys at −12.6 Â°C.JOURNAL, 10.1002/zaac.19120740115, van Rossen, G. L. C. M., van Bleiswijk, H., Ãœber das Zustandsdiagramm der Kalium-Natriumlegierungen, Zeitschrift für Anorganische Chemie, 74, 1912, 152–156,weblink ]]Liquid sodium is used as a heat transfer fluid in some types of nuclear reactorsSodium as a Fast Reactor Coolant {{webarchive|url=https://web.archive.org/web/20130113134710weblink |date=13 January 2013 }} presented by Thomas H. Fanning. Nuclear Engineering Division. U.S. Department of Energy. U.S. Nuclear Regulatory Commission. Topical Seminar Series on Sodium Fast Reactors. May 3, 2007 because it has the high thermal conductivity and low neutron absorption cross section required to achieve a high neutron flux in the reactor.WEB,weblink Sodium-cooled Fast Reactor (SFR), Office of Nuclear Energy, U.S. Department of Energy, 18 February 2015, The high boiling point of sodium allows the reactor to operate at ambient (normal) pressure, but the drawbacks include its opacity, which hinders visual maintenance, and its explosive properties.BOOK, Fire and Explosion Hazards, Research Publishing Service, 2011, 978-981-08-7724-8, 363, 2011, Radioactive sodium-24 may be produced by neutron bombardment during operation, posing a slight radiation hazard; the radioactivity stops within a few days after removal from the reactor.BOOK, Simulation and Optimization Methods in Risk and Reliability Theory, Nova Science Publishers, 2009, Pavel Solomonovich Knopov, Panos M. Pardalos, 978-1-60456-658-1, 150, 2009, If a reactor needs to be shut down frequently, NaK is used; because NaK is a liquid at room temperature, the coolant does not solidify in the pipes.BOOK, Proceedings of the Heat Transfer and Fluid Mechanics Institute, McKillop, Allan A., Stanford University Press, 1976, 97, 978-0-8047-0917-0, 1976, In this case, the pyrophoricity of potassium requires extra precautions to prevent and detect leaks.BOOK, Reactor Handbook: Engineering, U.S. Atomic Energy Commission, Interscience Publishers, 325, 2, Another heat transfer application is poppet valves in high-performance internal combustion engines; the valve stems are partially filled with sodium and work as a heat pipe to cool the valves.PATENT, US, US2949907 A, Coolant-filled poppet valve and method of making same, 23 Aug 1960, Tauschek Max J,

Biological role

Biological role in humans

In humans, sodium is an essential mineral that regulates blood volume, blood pressure, osmotic equilibrium and pH; the minimum physiological requirement for sodium is 500 milligrams per day.WEB,weblinkweblink" title="web.archive.org/web/20110823114818weblink">weblink 2011-08-23, Sodium, Northwestern University, 2011-11-21,

Nutrition

Diet

Sodium chloride is the principal source of sodium in the diet, and is used as seasoning and preservative in such commodities as pickled preserves and jerky; for Americans, most sodium chloride comes from processed foods.WEB,weblink Sodium and Potassium Quick Health Facts, health.ltgovernors.com, Other sources of sodium are its natural occurrence in food and such food additives as monosodium glutamate (MSG), sodium nitrite, sodium saccharin, baking soda (sodium bicarbonate), and sodium benzoate.WEB,weblink Sodium in diet, MedlinePlus, US National Library of Medicine, 5 October 2016,

Dietary recommendations

The U.S. Institute of Medicine set its Tolerable Upper Intake Level for sodium at 2.3 grams per day,WEB, Reference Values for Elements,weblink Dietary Reference Intakes Tables, Health Canada, but the average person in the United States consumes 3.4 grams per day.BOOK, U.S. Department of Agriculture, U.S. Department of Health and Human Services, United States Department of Agriculture, United States Department of Health and Human Services, Dietary Guidelines for Americans, 2010, 22, 7th, December 2010,weblink" title="web.archive.org/web/20110206111821weblink">weblinkweblink 6 February 2011, 2011-11-23, 978-0-16-087941-8, 738512922,

Health

Studies have found that lowering sodium intake by 2 g per day tends to lower systolic blood pressure by about two to four mm Hg.JOURNAL, 15369026, 2004, Geleijnse, J. M., Kok, F. J., Grobbee, D. E., Impact of dietary and lifestyle factors on the prevalence of hypertension in Western populations, 14, 3, 235–239, European Journal of Public Health, 10.1093/eurpub/14.3.235,weblink It has been estimated that such a decrease in sodium intake would lead to between 9 and 17% fewer cases of hypertension.Hypertension causes 7.6 million premature deaths worldwide each year.JOURNAL, 18456100, 2008, Lawes, C. M., Vander Hoorn, S., Rodgers, A., International Society of Hypertension, Global burden of blood-pressure-related disease, 2001, 371, 9623, 1513–1518, 10.1016/S0140-6736(08)60655-8, Lancet,weblink 25 October 2017,weblink" title="web.archive.org/web/20151026130602weblink">weblink 26 October 2015, dead, dmy-all, 10.1.1.463.887, (Note that salt contains about 39.3% sodiumBOOK, Armstrong, James, General, Organic, and Biochemistry: An Applied Approach,weblink 2011, Cengage Learning, 978-1-133-16826-3, 48–, {{--}}the rest being chlorine and trace chemicals; thus, 2.3 g sodium is about 5.9 g, or 5.3 ml, of salt{{--}}about one US teaspoon.Table Salt Conversion. Traditionaloven.com. Retrieved on 2015-11-11.WEB,weblink Use the Nutrition Facts Label to Reduce Your Intake of Sodium in Your Diet, 3 January 2018, US Food and Drug Administration, 2 February 2018, ) The American Heart Association recommends no more than 1.5 g of sodium per day.WEB,weblink How much sodium should I eat per day?, American Heart Association, 2016, 15 October 2016, One study found that people with or without hypertension who excreted less than 3 grams of sodium per day in their urine (and therefore were taking in less than 3 g/d) had a higher risk of death, stroke, or heart attack than those excreting 4 to 5 grams per day. Levels of 7 g per day or more in people with hypertension were associated with higher mortality and cardiovascular events, but this was not found to be true for people without hypertension.JOURNAL, Andrew Mente, etal, Associations of urinary sodium excretion with cardiovascular events in individuals with and without hypertension: a pooled analysis of data from four studies, The Lancet, 2016, 10.1016/S0140-6736(16)30467-6, 27216139, 388, 10043, 465–75, The US FDA states that adults with hypertension and prehypertension should reduce daily intake to 1.5 g.The renin–angiotensin system regulates the amount of fluid and sodium concentration in the body. Reduction of blood pressure and sodium concentration in the kidney result in the production of renin, which in turn produces aldosterone and angiotensin, which stimulates the reabsorption of sodium back into the bloodstream. When the concentration of sodium increases, the production of renin decreases, and the sodium concentration returns to normal.BOOK, McGuire, Michelle, Beerman, Kathy A., Nutritional Sciences: From Fundamentals to Food, 2011, Cengage Learning, 978-0-324-59864-3, 546, 472704484, The sodium ion (Na+) is an important electrolyte in neuron function, and in osmoregulation between cells and the extracellular fluid. This is accomplished in all animals by Na+/K+-ATPase, an active transporter pumping ions against the gradient, and sodium/potassium channels.BOOK, Campbell, Neil, Biology, 1987, 978-0-8053-1840-1, 795, Benjamin/Cummings, Sodium is the most prevalent metallic ion in extracellular fluid.BOOK, Srilakshmi, B., Nutrition Science, 2006, New Age International,weblink 978-81-224-1633-6, 2nd, 318, 173807260, Unusually low or high sodium levels in humans are recognized in medicine as hyponatremia and hypernatremia. These conditions may be caused by genetic factors, ageing, or prolonged vomiting or diarrhea.BOOK, Pohl, Hanna R., Wheeler, John S., H. Edward, Murray, Astrid Sigel, Helmut Sigel, Roland K. O. Sigel, Interrelations between Essential Metal Ions and Human Diseases, Metal Ions in Life Sciences, 13, 2013, Springer, 29–47, 10.1007/978-94-007-7500-8_2, 24470088, Sodium and Potassium in Health and Disease, 978-94-007-7499-5,

Biological role in plants

In C4 plants, sodium is a micronutrient that aids metabolism, specifically in regeneration of phosphoenolpyruvate and synthesis of chlorophyll.WEB, Kering, M. K.,weblink Manganese Nutrition and Photosynthesis in NAD-malic enzyme C4 plants Ph.D. dissertation, University of Missouri-Columbia, 2008, 2011-11-09, In others, it substitutes for potassium in several roles, such as maintaining turgor pressure and aiding in the opening and closing of stomata.JOURNAL, Subbarao, G. V., Ito, O., Berry, W. L., Wheeler, R. M., Sodium—A Functional Plant Nutrient, Critical Reviews in Plant Sciences, 22, 391–416, 2003, 10.1080/07352680390243495, 5, Excess sodium in the soil can limit the uptake of water by decreasing the water potential, which may result in plant wilting; excess concentrations in the cytoplasm can lead to enzyme inhibition, which in turn causes necrosis and chlorosis.JOURNAL, Zhu, J. K., Plant salt tolerance, Trends in Plant Science, 6, 2, 66–71, 2001, 11173290, 10.1016/S1360-1385(00)01838-0, In response, some plants have developed mechanisms to limit sodium uptake in the roots, to store it in cell vacuoles, and restrict salt transport from roots to leaves;WEB,weblink Plants and salt ion toxicity, Plant Biology, 2010-11-02, excess sodium may also be stored in old plant tissue, limiting the damage to new growth. Halophytes have adapted to be able to flourish in sodium rich environments.

Safety and precautions

{{Chembox| show_footer = no|Section7={{Chembox Hazards| ExternalSDS =| GHSPictograms = {{GHS02}}{{GHS05}}| GHSSignalWord = Danger
260|314}}223280370+378WEBSITE=SIGMA-ALDRICH, | NFPA-H = 3| NFPA-F = 2| NFPA-R = 2| NFPA-S = wHazard Rating Information for NFPA Fire Diamonds {{webarchive>url=https://web.archive.org/web/20150217135922weblink |date=17 February 2015 }}. Ehs.neu.edu. Retrieved on 2015-11-11.
}}
}}Sodium forms flammable hydrogen and caustic sodium hydroxide on contact with water;BOOK, Angelici, R. J., Synthesis and Technique in Inorganic Chemistry, University Science Books, Mill Valley, CA, 1999, 978-0-935702-48-4, ingestion and contact with moisture on skin, eyes or mucous membranes can cause severe burns.BOOK, Sodium Explosion Critically Burns Firefighters: Newton, Massachusetts, U. S. Fire Administration, Routley, J. Gordon, FEMA, 2013, BOOK, Prudent Practices in the Laboratory: Handling and Disposal of Chemicals, National Research Council (U.S.). Committee on Prudent Practices for Handling, Storage, and Disposal of Chemicals in Laboratories, National Academies, 1995, 390, Sodium spontaneously explodes in the presence of water due to the formation of hydrogen (highly explosive) and sodium hydroxide (which dissolves in the water, liberating more surface). However, sodium exposed to air and ignited or reaching autoignition (reported to occur when a molten pool of sodium reaches about 290 Â°Cweblink displays a relatively mild fire. In the case of massive (non-molten) pieces of sodium, the reaction with oxygen eventually becomes slow due to formation of a protective layer.WEB,weblink BEHAVIOUR IN THE ATMOSPHERE OF THE AEROSOL FROM A SODIUM FIRE, W. S., Clough, J. A., Garland, 1 July 1970, www.osti.gov, Fire extinguishers based on water accelerate sodium fires; those based on carbon dioxide and bromochlorodifluoromethane should not be used on sodium fire. Metal fires are Class D, but not all Class D extinguishers are workable with sodium. An effective extinguishing agent for sodium fires is Met-L-X. Other effective agents include Lith-X, which has graphite powder and an organophosphate flame retardant, and dry sand.BOOK, Industrial fire prevention and protection, Ladwig, Thomas H., Van Nostrand Reinhold, 1991, 978-0-442-23678-6, 178, 1991, Sodium fires are prevented in nuclear reactors by isolating sodium from oxygen by surrounding sodium pipes with inert gas.BOOK, Sustainable and Safe Nuclear Fission Energy: Technology and Safety of Fast and Thermal Nuclear Reactors, Günter Kessler, Springer Science & Business Media, 2012, 978-3-642-11990-3, 446, illustrated, 8 May 2012, Pool-type sodium fires are prevented using different design measures called catch pan systems. They collect leaking sodium into a leak-recovery tank where it is isolated from oxygen.

See also

{{Subject bar|portal=Chemistry|book1=Sodium|book2=Period 3 elements|book3=Alkali metals|book4=Chemical elements (sorted alphabetically)|book5=Chemical elements (sorted by number)|commons=y|wikt=y|wikt-search=sodium|v=y|v-search=Sodium atom|b=y|b-search=Wikijunior:The Elements/Sodium}}

References

{{reflist|30em}}

Bibliography

  • {{Greenwood&Earnshaw2nd}}

External links

{{clear}}{{Compact periodic table}}{{Sodium compounds}}{{Use dmy dates|date=November 2010}}{{good article}}{{Authority control}}


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